Thursday, 26 February 2015

3.3.2 - Laboratory Activity: Position of Carbon in the Reactivity Series


Laboratory Activity 3.3.2:
Position of Carbon in the Reactivity Series
Aim: To determine the position of carbon in the reactivity series.
Problem statement: How to determine the position of carbon in the reactivity series?
Hypothesis: If carbon is more reactive than the metal, it can remove oxygen from its metal oxides.
Variable:
» Fixed variable : Carbon powder
» Manipulated variable : Metal oxides
» Responding variable : Ability to reduce

Material:
» Carbon powder
» Copper (II) oxide
» Zinc oxide
» Lead (II) oxide
» Magnesium oxide
» Aluminium oxide

Apparatus:
» Crucible
» Tripod stand
» Spatula
» Bunsen burner
» Fireclay triangle
Procedure:

► The animation below shows the arrangement of the apparatus and the observation of the experiment.

►
1. One spatula of lead (II) oxide is mixed with one spatula of carbon powder in a crucible and heated strongly on a fireclay triangle placed on a tripod stand.
2. The changes are noted and recorded.
3. The experiment is repeated by replacing lead (II) oxide with other metal oxide.
Observation:

►
Mixture Observation
Carbon + lead (II) oxide A reddish glow and shinning grey metallic solid is formed.
Carbon + aluminium oxide No reaction
Carbon + zinc oxide The mixture glow and grey deposits is formed.
Analysis:

► Carbon reduces lead (II) oxide, copper (II) oxide and zinc oxide. Therefore carbon must have occupied a higher position than lead and zinc in the reactivity series.
○ C(s) + 2ZnO(s) → 2Zn(s) + CO2(g)
○ C(s) + 2PbO(s) → 2Pb(s) + CO2(g)

► Carbon does not reduce aluminium oxide. This show that carbon having the lower position than aluminium in the reactivity series.

► Therefore, the position of carbon in the reactivity series is between aluminium and zinc.
Conclusion:

► Carbon is places between aluminium and zinc in the reactivity series.


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