Wednesday, 21 January 2015

6.6 The Electrochemical Series

Electrochemical series
■ Electrochemical series

► A series of elements arrangement according to the order of decreasing tendency to release electrons.

► Element located at higher position in the electrochemical series:
○ More electropositive
○ Has a greater tendency to form cations by donating electrons
○ More reactive
■ Electrochemical series can be constructed based on:

► The potential difference between two metals in the voltaic cell.
○ Metals that further apart in the electrochemical series produce a higher voltage that metals which are close to each other.

► The displacement of metals by another more reactive metals from its salt solution.
○ The metal which is more electropositive will displace the less electropositive metal from its salt solution.
○ Example: Displacement of copper, Cu, from copper(II) nitrate solution by zinc.
○ Chemical equation: ZN(s) + CU(NO3)2(aq) → Zn(NO3)2(aq) + Cu(s)
○ Nitrate ion, NO-3 does not take part in the chemical reaction
○ Thus, ionic equation can be written as:Zn(s) + Cu2+(aq) → Zn2+(aq) + Cu(s)
Laboratory Activity 6.6.1: Constructing the electrochemical series based on the potential difference between two metals
Laboratory Activity 6.6.2: To construct the electrochemical series based on the displacement of metals
■ This video contains information on the electrochemical series.



⇲ For exercise(objective and subjective), download for free on Android OS.

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