Saturday, 17 January 2015

5.2 Formation of Ionic Bonds

Formation of cation and anion
■ Formation of cation and anion

► An atom is neutral because it has an equal number of protons and electrons.

► An ion formed when an atom donates or accepts one or more electrons.

■ Formation of cation

►

► When an atom donates electrons, it becomes positively charged as there are more protons than electrons in it.

► A positively charged ion or cation is obtained.

► M → Mn+ + ne
■ Formation of anion

►

► When an atom accepts electrons, it becomes negatively charged as there are more electrons than protons in it.

► A negatively charged ion or anion is obtained

► A + ne → An-
Formation of ionic bonds
■ Formation of ionic bonds

► Electrons are transferred from a metal to a non-metal.

► The metal donates its valence electron(s) to attain the noble gas stability. Positive ions (cation) are formed.

► The non-metal received the electron(s) to attain the noble gas stability. Negative ion (anion) are formed.

► The positive and negative ions are held together by strong electrostatic forces of attraction.

► This strong electrostatic forces of attraction between ions of opposite charges is known as ionic bond.

► The animation below shows the formation of sodium chloride (NaCl), magnesium oxide (MgO), and sodium oxide (NaO2).

■ This video contains information on the formation of ionic bonds.

Laboratory Activity 5.2.1: Preparation of Ionic Compounds
Determining the ionic compound formulae
■ Formulae of an ionic compound.

► Metal atoms will release their valence electrons to achieve the stable electron arrangement as in the inert gases.

► Non-metal atoms will accept electrons in order to achieve the stable electron arrangement of the inert gases.

► For cations Mb+ and anions Xa-, the formula of an ionic compound formed between them is written as MaNb.

► The total positive charge of the cation must be equal to the negative charge of the anion in an ionic compound.

► Hence, the formula of an ionic compound formed between them can also be derived as follows :
aMb+ + bXa- → MaNb

✍ Worked-example 5.2(a)
Complete the following table to show the written ionic compound formulae.

Solution 
Atom Proton number Electron arrangement Ion formula Atom Proton number Electron arrangement Ion formula
A 3 2.1 A+ V 9 2.7 V-
B 11 2.8.1 B+ W 8 2.6 W2-
C 12 2.8.2 C2+ X 17 2.8.7 X-
D 20 2.8.8.2 D2+ Y 9 2.7 Y-
E 19 2.8.8.1 E+ Z 17 2.8.7 Z-


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