Wednesday, 7 January 2015

4.4 Group 17 Elements

Physical properties
■ Elements of Group 17 also known as halogens

►
Flourine, F
Chlorine, Cl
Bromine, Br
Iodine, I
Astatine, At

► The following mnemonic method can be used to memorize the sequence of elements in Group 17.
○ Fairy Clowns Broil Innocent Ants.
■ Physical properties of halogens

►
Elements Proton number Atomic radius (nm) Melting point (℃) Boiling point (℃) Density (gcm-3) Color
Flourine, Fl 9 0.06 -220 -187 1.12 Light yellow
Chlorine, Cl 17 0.10 -102 -34 1.57 Greenish yellow
Bromine, Br 35 0.12 -7.2 59 3.13 Reddish-brown
Iodine, I 53 0.14 114 183 4.95 Purple-black

► Low melting points and boiling point.
○ All halogens exist as diatomic molecules gas (F2, Cl2, Br2, I2, At2)

► Do not conduct electricity

► Weak conductors of heat

► Low density

► The animation below shows the changes in physical properties of Group 17 elements down the group.

Chemical properties
■ Arrangement of electron in halogen elements.

Element Electron configuration Arrangement of electron
Flourine 2.7
Chlorine 2.8.7
Bromine 2.8.18.7
Iodine 2.8.18.18.7
Astatine 2.8.18.32.18.7
■ Chemical reaction.

► Alkali halogens elements show similar properties when reacting with certain compounds.
○ Halogens react with water to form two acid.
Laboratory Activity 4.4.1: Studying the reaction of chlorine, bromine and iodine with water
○ Halogens react with hot iron to form a brown solid, iron (II) halides.
Laboratory Activity 4.4.2: Studying the reaction of halogens with iron wool
○ Halogens react with sodium hydroxide solution to form sodium halide, sodium halate (I) and water.
Laboratory Activity 4.4.3: Studying the reaction of halogens with aqueous sodium hydroxide solution

► Brief explanation on the reaction of halogen.
○ All halogens have 7 valence electron.
○ They receive an electron to form an anion or negative ion in order to attain the stable octet or noble gas electron arrangement.

► The reactivity of halogens decreases as down the group.

► The animation below shows the explanation on the changes on the reactivity of alkali metals.

■ This video contains information about the physical properties and the reactions of the Group 17 elements.


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