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Wednesday, 7 January 2015

4.3 Group 1 Elements

Physical properties
■ Elements of Group 1

►
Lithium, Li
Natrium, Na
Kalium, K
Rubidium, Rb
Caesium, Cs
Francium, Fr

► The following mnemonic method can be used to memorize the sequence of elements in Group 1.
○ Little Nasty Kids Rub Cat's Fur
■ Physical properties of alkali metals

► All alkali metals are grey in colour with shining surfaces just like other metals.

► All alkali metals are soft and can cut easily.
Elements Density (gcm-3) Melting point (℃) Boiling point (℃) Atomic radius (nm)
Lithium, Li 0.534 186 1609 0.133
Natrium, Na 0.970 98 880 0.157
Kalium, K 0.860 64 760 0.203
Rubidium, Rb 1.530 39 700 0.216
Saesium, Cs 1.900 29 670 0.235

► All alkali metal conduct heat and electricity.

► All alkali metals have high melting and boiling point.
○ The melting and boiling point are not as high as other metals.
○ The melting and boiling point decrease down the group. This is because as the atomic radius increases, the bonds between the atoms become weaker.

► The atomic radius and density of elements increase down the group.
○ An increase in the number of filled electron shells will result in increased atomic size, mass and density.

► The animation below shows the changes in physical properties of Group 1 elements down the group.


Chemical properties
■ Arrangement of electron in alkali metals.

Element Electron configuration Arrangement of electron
Lithium 2.1
Natrium 2.8.1
Kalium 2.8.8.1
Rubidium 2.8.18.8.1
Caesium 2.8.18.18.8.1
■ Chemical reaction.

► Alkali metals are very reactive elements and therefore must be kept in paraffin.

► All alkali metals shows similar properties when reacting with certain compounds.
○ All alkali metals react vigorously with water to produce alkaline metal hydroxide solution and hydrogen gas.
Laboratory Activity 4.3.1: Studying the reaction of alkali metals with oxygen
○ All alkali metals burn in oxygen gas rapidly to produce solid metal oxides.
Laboratory Activity 4.3.2: Studying the reaction of alkali metals with water
○ All alkali metals burn in halogen gas rapidly to produce white solid metal halides.
Laboratory Activity 4.3.3: Studying the reaction of alkali metals with halogen

► Brief explanation on the reaction of alkali metals.
○ All alkali metals have one valence electron.
○ They donate this electron to attain the noble gas stability.
Y→ Y++ e-

► The reactivity of alkali metals increases as down the group.

► The animation below shows the explanation on the changes on the reactivity of alkali metals.

■ This video contains information about the physical properties and the reactions of the Group 1 elements.









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